產品簡介:Acrylic Primer#1602 LANG丙烯酸底漆DetailsWe recommend applying a priming liquid to prepare any acrylic surface for repair or buildup.This product is specifically formulated to ensure uniform bonding,
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediay all contaminated clothing. Rinse skin with water/shower.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P362 Take off contaminated clothing and wash before use.
P370+P378In case of fire: Use CO2, for extinction.
Precautionary Statements – Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.
Precautionary Statements – Disposal
P501Dispose of contents/container in accordance with local regulation.
Hazards not otherwise classified (HNOC) Not applicable
Other InformationHarmful to aquatic life
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name
CAS No
Weight - %
Trade Secret
Methyl Methacrylate
80-62-6
<100
*
*Specific chemical weight has been
withheld as a trade secret.
4. FIRST AID MEASURES
First aid measures
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ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Use personal protective equipment as required. Ensure adequate ventilation. Remove any contaminated clothing and wash thoroughly before reuse.
Inhalation
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Keep patient warm and at
rest. Call a physician or poison control center immediay.
Eye contact
Immediay flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing
for at least 15 minutes. Call a physician immediay.
Ingestion
Do NOT induce vomiting. Drink plenty of water or milk immediay. Never give anything by mouth to an
unconscious person. Provide an estimate of the time at which the material was ingested and the amount of
the substance that was swallowed. Call a physician or poison control center immediay.
Skin Contact
Wash off immediay with plenty of soap and water. Take off contaminated clothing. Wash contaminated
clothing before reuse. If skin irritation or rash occurs, get medical advice/attention.
Most important symptoms and effects, both acute and delayed
Symptoms
May cause skin and eye irritation to the mucous membranes and upper respiratory tract.
Indication of any immediate medical attention and special treatment needed
Note to physicians
Treat symptoms conventionally, after thorough decontamination.
5. FIRE-FIGHTING MEASURES
Extinguishing Media
Suitable: Chemical foam, carbon dioxide (CO2), dry chemical
Unsuitable: Water spray
Specific hazards arising from the chemical
For bulk size >1L – High temperatures, inhibitor depletion, accidental impurities, or exposure to radiation or oxidizers may cause spontaneous polymerizing reaction generating heat/pressure. Closed containers may rupture or explode during a runaway polymerization. Use a water spray or fog to reduce or direct vapors. Extremely flammable. Vapors are heavier than air and may spread along the floors. Vapors may travel to source of ignition and flash back. Heat/impurities may cause pressure to build and/or rupture closed containers, spreading fire, increasing risk or burns/injuries.
Hazardous Combustion Products:Carbon oxides
Sensitivity to Mechanical Impact:No
Sensitivity to Static Discharge:Yes
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Fight fire from a safe location.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions
Environmental precautionsPrevent product from entering drains. Spillages or uncontrolled discharges into watercourses must
be alerted to the appropriate regulatory body.
Methods and material for containment and clean-up
Method for containmentAbsorb with earth, sand or other non-combustible material and transfer to containers for later
disposal. DO NOT use combustible materials such as sawdust.
Method for clean-upUse only non-sparking tools. Wash all affected areas with plenty of warm water and soap.
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If anticipated that prolonged and repeated skin contact will occur during use of this product, wear gloves for routine industrial use. If necessary, refer to US OSHA 29CFR SS1910.138 or the appropriate standards of Canada or the EC member states. Wear suitable protective clothing.
Depending on the use of this product, safety glasses or goggles may be worn. If necessary, refer to US OSHA 29CFR SS1910.133, Canadian standards or the European Standard EN 166. Ensure that an eyewash station, sink or washbasin is available in case of exposure to eyes.
Material has strong solvent properties and can soften paint and rubber.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Consideration should be given to the work procedures involved and the potential extent of exposure as they may determine whether a higher level of protection is required. The following information is given as general guidance.
Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat, sparks, flame and other sources of ignition (i.e. pilot lights, electric motors and static electricity). Protect from direct sunlight. Keep container closed to prevent water absorption and contamination. Methacrylate stored in bulk must be kept in contact with air (oxygen). Keep at a temperature not exceeding 25°C.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling Observe precautions found on the label. Keep containers closed when not in use. All equipmentused when handling the product must be grounded. Use non-sparking hand tools and explosion-proof electrical equipment. Avoid contact with skin and eyes. Avoid breathing vapors or mists. Use only in well-ventilated areas. Vapors are heavier than air and may travel along the floor and in the bottom of containers. Take precautionary measures against static discharges. Wash thoroughly after handling. Use personal protection recommended in Section 8. Contaminated work clothing should not be allowed out of the workplace. Keep away from heat, sparks, open flames, and hot surfaces. NO SMOKING.
Conditions for safe storage, including any incompatibilities
Storage Conditions
Packaging materials
Incompatible materials
Exposure guidelines
Chemical Name
ACGIH TLV
OSHA PEL
NIOSH IDLH
Methyl Methacrylate
S 100 ppm
TWA:100 ppm
IDLH: 1,000 ppm
80-62-6
TWA: 50 ppm
TWA: 410 mg/m3
TWA: 100 ppm
TWA: 410 mg/m3
Appropriate engineering controls
Engineering controls Apply technical measures to comply with the occupational exposure limits.Eyewash stations
Individual protection measures, such as personal protective equipment
Eye / face protection
Skin and body protection
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Respiratory protection
Wear suitable respiratory equipment if exposure to levels above the occupational exposure limit is
likely. A suitable mask with filter type A may be appropriate. In the event of formation of particularly
high levels of vapor, a self-contained breathing apparatus may be appropriate.
General hygiene considerations
Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state
Liquid
Odor
Acrid
Appearance
Liquid
Odor threshold
Not determined
Color
Clear
Property
Values
Remarks / Method
pH
Not determined
Melting point /
freezing point
Not determined
Boiling point / boiling range
101°C / 214° F
Flash point
11.5°C / 52.7°F
Evaporation rate
3.1
Butyl acetate = 1
Flammability (solid, gas)
n/a (liquid)
Flammability limits in air
Upper flammability limit
12.5%
Lower flammability limit
2.12%
Vapor pressure
28mm Hg
@ 20°C
Vapor density
3.5
@15.5°C (Air = 1)
Specific gravity
0.891
Water = 1
Water solubility
1.6 wt%
Solubility in other solvents
Not determined
Partition coefficient
Not determined
Autoignition temperature
421°C / 790°F
Decomposition temperature
Not determined
Kinematic viscosity
Not determined
Dynamic viscosity
Not determined
Explosive properties
Not determined
Oxidizing properties
Not determined
Other information
Density
0.891 g/mL
10. STABILITY AND REACTIVITY
Reactivity
Not reactive under normal conditions
Chemical stabilityUnstable / reactive upon depletion of inhibitor
Possibility of hazardous reactions
None under normal processing
Hazardous polymerization Hazardous polymerization may occur. Monomer vapors are inhibited and may form polymers in vent orflame arresters, resulting in blockage of vents.
Conditions to avoid
Temperatures above 25°C (77°F), localized heat sources (e.g. drum or band heaters), oxidizing conditions, freezing conditions, direct sunlight, ultraviolet radiation, inert gas blanketing
Medical Devices Directive 93/42/EEC - Class I Medical Devices
US Federal Regulations
Chemical Name
CAS
Weight %
SARA 313 Threshold Values %
Methyl Methacrylate
80-62-6
< 100
1.0
SARA 311 / 312 Hazard Categories
Chemical Name
CWA – Reportable
CWA – Toxic
CWA – Priority
CWA – Hazardous
Quantities
Pollutants
Pollutants
Substances
Methyl Methacrylate
1,000 lb.
-
-
X
80-62-6
Chemical Name
Hazardous Substances
CERCLA /
Reportable Quantity (RQ)
RQs
SARA RQ
Final
Methyl Methacrylate
1,000 lb.
-
1,000 lb. / 454 kg
80-62-6
US State Right-to-Know Regulations
Chemical Name
CAS
New Jersey
Massachusetts
Pennsylvania
Methyl Methacrylate
80-62-6
X
X
X
16. OTHER INFORMATION
NFPA
Health Hazards
Flammability
Instability
2
3
2
HMIS
Health Hazards
Flammability
Physical Hazards
2
3
2
Issue Date
26-Sept-2014
Revision Date
14-July-2015
Revision Note
Section 2 – revise classification categories, revise some Hazard Statements and Precautionary Statements,,
add hazardous component for labeling info
Information to be updated in due course
Hazard pictograms listed in this SDS to be added to product label
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release. It is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.